We can
redirect to controller actions from Global.asax in ASP.Net MVC 5 using the
method - RedirectToControllers. The RedirectToControllers() method provided by MVC 2 + versions. 
Example, it might help you to understand more about the same. 
Example, it might help you to understand more about the same.
/// <summary>
/// gets
the authentication cookie
/// if
the cookie is null then redirect to controller action
/// </summary>
protected void
Application_AuthenticateRequest(Object sender, EventArgs e)
{
    // Get the authentication
cookie.
    string
cookieName = FormsAuthentication.FormsCookieName;
    HttpCookie authCookie =
Context.Request.Cookies[cookieName];
    // If the cookie is null
then redirect to the controller action.
    if
(authCookie == null)
    {
        RedirectToControllers("Account",
"Login");
    }
} 
///<summary>
///Clear
the response. 
///
Clear the server errors. 
///
Create the route using RouteData (controller/action)
///
Name of controller where you wants to redirect
/// </summary>
private void
RedirectToControllers(string control, string action)
{
    Response.Clear();
    Server.ClearError();
    var
route = new RouteData();
    route.Values["controller"]
= control;
    route.Values["action"]
= action;
    // Name of controller
where you want to redirect.
    IController controller = new
AlertsController();
    var
RequestCont = new RequestContext(new
HttpContextWrapper(Context), route);
    controller.Execute(RequestCont);
}